Abstract

Sequestrating CO2 in deep saline aquifers is maybe the most effective option to mitigate CO2 emission. The storage capacity of CO2 is the key factor for site selection before a project is carried out. Most of the existing methods are for assessment of CO2 sequestered by stratigraphic and structural trapping, as well as residual trapping and solubility trapping. In this study, we used a new method that considers CO2 consumption through geochemical reactions with minerals of reservoir rocks, mainly sandstones. Contribution of storage capacity from carbonate mineral mainly refers to calcite is excluded. That is because lifetime of calcite (the whole time from reaction starting to calcite running out) is very short contrast with geological time-scale or it is a temporary trapping. The geochemical reactions between CO2 and feldspar minerals with thousand-year lifetime are regarded as the permanent methods for trapping CO2. CO2 consumptions by K-feldspar, albite, and anorthite are assessed with volume method based on corresponding geochemical reactions. Storage efficiency factor is also considered as one of the most important parameters in the reaction formula and it depends on specific surface area of minerals contacting with formation water and kinetics of precipitation and dissolution of minerals. We assessed the CO2 storage capacity of mineral trapping in Baokang sedimentary system, south Songliao Basin through the detailed analysis of geological data in this area. The calculated results show the total CO2 storage capacity of mineral trapping of the study area is 457.5–5114.5 Mt and the corresponding storage efficiency factor is 1%. The CO2 consumed by albite makes up more than 60% of the total storage capacity and it is about 30% for anorthite.

Abstract

Two-dimensional glass model experiments are used to investigate the residual trapping mechanism of CO2 stored in saline aquifers. For this purpose, two proxy fluids are chosen to simulate the CO2-brine behavior under reservoir conditions. The first set of experiments is carried out by flooding n-heptane in a mixture of glycerol and water inside a glass bead porous media. Fluids and porous materials are designed so that the dimensionless groups are in the range of real storage sites. Another set of proxy fluid consists of dodecane and a different mixture of glycerol and water, representing the second wettability condition for the system. The size of the glass beads chosen was fine (70–110 μm) in order to investigate residual trapping phenomena. For each set, after complete drainage process, an imbibition process is performed and in each time step, images are taken from the phenomena. The images are processed using a red, green, blue (RGB) color concept using a Matlab code that was developed for this study. By using this process, it is possible to measure the residual trapping of CO2 proxy fluid for each test and to determine the saturation profile in the model. Tests are carried out at various imbibition and drainage rates to study the effect of the rate on the results. Fine-scale numerical simulation models are constructed for comparison with experimental results. Good agreement is obtained between the simulation results and the image processing estimations, as well as the readings from the material balances during the experiments. This study could provide a framework for modeling different reservoir conditions for residual trapping mechanism and the impact of different parameters in future studies.